Organocatalytic β-Azidation of Enones Initiated by an Electron-Donor–Acceptor Complex
| dc.contributor.author | Shirke, R.P. | |
| dc.contributor.author | Ramasastry, S.S.V. | |
| dc.date.accessioned | 2020-12-04T04:59:14Z | |
| dc.date.available | 2020-12-04T04:59:14Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | An operationally straightforward organocatalytic β-azidation of α,β-unsaturated ketones is described. Reaction of the Zhdankin azidoiodane with enones in the presence of a catalytic amount of an amine provides β-azido ketones via the formation of an electron-donor–acceptor complex. The application of this protocol is demonstrated through one-step elaborations leading to the synthesis of unprecedented classes of 1,2,3-triazoles. | en_US |
| dc.identifier.citation | Organic Letters, 19(19), pp. 5482-5485 | en_US |
| dc.identifier.other | https://doi.org/10.1021/acs.orglett.7b02861 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.orglett.7b02861 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2636 | |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.subject | Azides | en_US |
| dc.subject | Hydrocarbons | en_US |
| dc.subject | Organocatalytic | en_US |
| dc.subject | Electron-Donor–Acceptor | en_US |
| dc.title | Organocatalytic β-Azidation of Enones Initiated by an Electron-Donor–Acceptor Complex | en_US |
| dc.type | Article | en_US |