Can Remote N‐Heterocyclic Carbenes Coordinate with Main Group Elements? Synthesis, Structure, and Quantum Chemical Analysis of N+‐Centered Complexes
| dc.contributor.author | Mandal, S.K. | |
| dc.date.accessioned | 2020-11-23T08:56:13Z | |
| dc.date.available | 2020-11-23T08:56:13Z | |
| dc.date.issued | 2018 | |
| dc.description | Only IISERM authors are available in the record. | |
| dc.description.abstract | Remote N-heterocyclic carbenes (rNHCs), such as N-methyl-4-pyridylidene, are known to form coordination complexes with TMs. Herein, it is established that rNHCs can also coordinate to the N+ centre. Synthesis of some novel divalent NI complexes with the general formula (rNHC)→N+←(NHC) and (rNHC)→N+←(rNHC) was achieved, and X-ray diffraction studies supported the coordination bond character between the rNHCs and the N+ centre. Quantum chemical analysis established the presence of divalent NI character at the central nitrogen in these systems | en_US |
| dc.identifier.citation | Chemistry - A European Journal, 24(24), pp. 6418-6425 | en_US |
| dc.identifier.other | https://doi.org/10.1002/chem.201705999 | |
| dc.identifier.uri | https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201705999 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2050 | |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley-VCH Verlag | en_US |
| dc.subject | Carbene ligands | en_US |
| dc.subject | Divalent NI compounds | en_US |
| dc.subject | Donor–acceptor systems | en_US |
| dc.subject | Quantum chemical analysis | en_US |
| dc.title | Can Remote N‐Heterocyclic Carbenes Coordinate with Main Group Elements? Synthesis, Structure, and Quantum Chemical Analysis of N+‐Centered Complexes | en_US |
| dc.type | Article | en_US |