Glaser–Eglinton–Hay sp–sp coupling and macrocyclization: construction of a new class of polyether macrocycles having a 1,3-diyne unit
| dc.contributor.author | Naveen | |
| dc.contributor.author | Babu, S.A. | |
| dc.contributor.author | Kaur, Gurpreet | |
| dc.contributor.author | Aslam, N.A. | |
| dc.contributor.author | Karanam, M. | |
| dc.date.accessioned | 2020-12-12T05:07:50Z | |
| dc.date.available | 2020-12-12T05:07:50Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Glaser-Eglinton-Hay-type sp-sp coupling, macrocyclization and the construction of skeletally interesting, 18-27 membered, polyether macrocycles having a 1,3-diyne unit-based cylindrical backbone are reported. The utility of polyether macrocycles having the 1,3-diyne units is shown by incorporating isoxazole and thiophene moieties into the macrocycles. The structures of representative crown ether/polyether-type macrocycles were unambiguously established from single crystal X-ray structure analyses. Investigation of the X-ray structures of representative macrocycles revealed that the 1,3-diyne unit was not linear and was found to be bent. | en_US |
| dc.identifier.citation | RSC Advances, 4(36), pp.18904-18916 . | en_US |
| dc.identifier.other | https://doi.org/10.1039/C4RA02174F | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2014/RA/C4RA02174F#!divAbstract | |
| dc.identifier.uri | http://hdl.handle.net/123456789/3068 | |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | Macrocyclization | en_US |
| dc.subject | 1,3-diyne unit | en_US |
| dc.subject | Polyether | en_US |
| dc.subject | Macrocycles | en_US |
| dc.title | Glaser–Eglinton–Hay sp–sp coupling and macrocyclization: construction of a new class of polyether macrocycles having a 1,3-diyne unit | en_US |
| dc.type | Article | en_US |