N-Heterocyclic Carbene Catalyzed 1,6-Conjugate Addition of Me3Si-CN to para-Quinone Methides and Fuchsones: Access to α-Arylated Nitriles
| dc.contributor.author | Goswami, P. | |
| dc.contributor.author | Singh, Gurdeep | |
| dc.contributor.author | Anand, R.V. | |
| dc.date.accessioned | 2020-12-03T08:53:26Z | |
| dc.date.available | 2020-12-03T08:53:26Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | An organocatalytic approach toward α-arylated nitriles using N-heterocyclic carbene (NHC) as a catalyst is described. This protocol comprises an NHC catalyzed activation of Me3Si-CN followed by 1,6-conjugate addition of cyanide to para-quinone methides (p-QMs) and fuchsones leading to α-diaryl- and α-triaryl nitriles in good to excellent yields. | en_US |
| dc.identifier.citation | Organic Letters, 19(8) | en_US |
| dc.identifier.other | 10.1021/acs.orglett.7b00508 | |
| dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/acs.orglett.7b00508 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2570 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | ACS Publications | en_US |
| dc.subject | Chemical reactions, | en_US |
| dc.subject | Nitrogen compounds | en_US |
| dc.title | N-Heterocyclic Carbene Catalyzed 1,6-Conjugate Addition of Me3Si-CN to para-Quinone Methides and Fuchsones: Access to α-Arylated Nitriles | en_US |
| dc.type | Article | en_US |