A cascade reaction of indolyl-migratory isocyanide insertion, scaffold rearrangement and redox-neutral event with isocyanide as a C(sp3)H–N synthon efficiently constructs indolylisoindolinones
| dc.contributor.author | Yadav, Hare Ram | |
| dc.contributor.author | Choudhury, Angshuman R. | |
| dc.date.accessioned | 2023-08-14T06:48:14Z | |
| dc.date.available | 2023-08-14T06:48:14Z | |
| dc.date.issued | 2022 | |
| dc.description | Only IISERM authors are available in the record | en_US |
| dc.description.abstract | Herein, we report a Pd(0)-catalyzed cascade reaction of intramolecular indolyl isocyanide-insertion, isocyanide-initiated scaffold-rearrangement with indolyl migration and redox-neutral process, which affords an efficient access to indolylisoindolinones. Isocyanide as a C(sp3)H–N synthon and the alkyl motif of isocyanide as a hydride source have been explored for the first time. | en_US |
| dc.identifier.citation | Chemical Communications, 58(84), 11827-11830 | en_US |
| dc.identifier.uri | https://doi.org/10.1039/d2cc04273h | |
| dc.identifier.uri | http://hdl.handle.net/123456789/4672 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | cascade reaction | en_US |
| dc.subject | isocyanide insertion | en_US |
| dc.subject | indolylisoindolinones | en_US |
| dc.title | A cascade reaction of indolyl-migratory isocyanide insertion, scaffold rearrangement and redox-neutral event with isocyanide as a C(sp3)H–N synthon efficiently constructs indolylisoindolinones | en_US |
| dc.type | Article | en_US |