Facile Access to Cyclopentadienes via Catalytic Intramolecular Palladium-Ene Reaction of 2,4-Pentadienyl Acetates
| dc.contributor.author | Bharadwaj, S.K. | |
| dc.contributor.author | Bankar, S.K. | |
| dc.contributor.author | Ramasastry, S.S.V. | |
| dc.date.accessioned | 2020-11-26T06:40:48Z | |
| dc.date.available | 2020-11-26T06:40:48Z | |
| dc.date.issued | 2018 | |
| dc.description.abstract | We have recently disclosed a palladium-catalyzed Trost–Oppolzer type Alder-ene reaction of 2,4-pentadienyl acetates for the synthesis of highly substituted cyclopentadienes and cyclopentene-fused aromatics. The overall transformation also represents an acid-free iso-Nazarov type cyclization. Herein, we provide the hypothesis and rationale behind this work, while highlighting the seminal contributions of Trost, Oppolzer and others towards the development of the palladium-ene reaction. | en_US |
| dc.identifier.citation | Synlett, 29(19), pp. 2456-2460 | en_US |
| dc.identifier.other | DOI: 10.1055/s-0037-1610552 | |
| dc.identifier.uri | https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0037-1610552 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2260 | |
| dc.language.iso | en | en_US |
| dc.publisher | Georg Thieme Verlag | en_US |
| dc.subject | Tsuji–Trost reaction | en_US |
| dc.subject | Metallo-ene reaction | en_US |
| dc.subject | Cyclopentanes | en_US |
| dc.subject | Iso-Nazarov reaction | en_US |
| dc.subject | Annulation | en_US |
| dc.title | Facile Access to Cyclopentadienes via Catalytic Intramolecular Palladium-Ene Reaction of 2,4-Pentadienyl Acetates | en_US |
| dc.type | Article | en_US |