Annulative Morita–Baylis–Hillman reaction to synthesise chiral dibenzocycloheptanes
| dc.contributor.author | Mondal, Atanu | |
| dc.contributor.author | Shivangi | |
| dc.contributor.author | Tung, Pinku | |
| dc.contributor.author | Waguldea, Siddhant V. | |
| dc.contributor.author | Ramasastry, S. S. V. | |
| dc.date.accessioned | 2023-08-18T10:58:12Z | |
| dc.date.available | 2023-08-18T10:58:12Z | |
| dc.date.issued | 2021 | |
| dc.description | Only IISER Mohali authors are available in the record | en_US |
| dc.description.abstract | We describe the first metal-free and organocatalytic strategy to access highly functionalised dibenzocycloheptanes via a phosphine-promoted annulative Morita–Baylis–Hillman (MBH) reaction. The method is manipulated to access to chiral dibenzocycloheptanes as well. This work represents a rare entry for the construction of seven-membered carbocycles via the MBH route. The realisation of several bioactive molecules possessing the dibenzocycloheptane core makes this an attractive strategy. | en_US |
| dc.identifier.citation | Chemical Communications, 57(73), 9260–9263. | en_US |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC02765D | |
| dc.identifier.uri | http://hdl.handle.net/123456789/4836 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | Publishing | en_US |
| dc.subject | Morita–Baylis–Hillman | en_US |
| dc.subject | dibenzocycloheptanes | en_US |
| dc.title | Annulative Morita–Baylis–Hillman reaction to synthesise chiral dibenzocycloheptanes | en_US |
| dc.type | Article | en_US |