Palladium-Catalyzed Double Activation and Arylation of 2° and 3° C(sp3)–H Bonds of the Norbornane System: Formation of a C–C Bond at the Bridgehead Carbon and Bridgehead Quaternary Stereocenter
| dc.contributor.author | Parella, R. | |
| dc.contributor.author | Babu, S.A. | |
| dc.date.accessioned | 2020-12-11T10:38:51Z | |
| dc.date.available | 2020-12-11T10:38:51Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | Pd-catalyzed activation and direct arylation of both 2° and the bridgehead 3° (sp3) C-H bonds and an unprecedented C-C bond formation at the bridgehead carbon of the norbornane system are reported. The assembly of bridgehead-substituted norbornane frameworks having contiguous stereocenters was accomplished. X-ray crystal structure analysis of representative molecules unambiguously established the stereochemistry. | en_US |
| dc.identifier.citation | Synlett, 25(10), pp.1395-1402. | en_US |
| dc.identifier.other | 10.1055/s-0033-1341242 | |
| dc.identifier.uri | https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0033-1341242 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/3060 | |
| dc.language.iso | en | en_US |
| dc.publisher | Georg Thieme Verlag | en_US |
| dc.subject | Arylation | en_US |
| dc.subject | Bridgehead substitution | en_US |
| dc.subject | C–H activation | en_US |
| dc.subject | Diastereoselectivity | en_US |
| dc.subject | Palladium | en_US |
| dc.subject | Stereoselective synthesis | en_US |
| dc.title | Palladium-Catalyzed Double Activation and Arylation of 2° and 3° C(sp3)–H Bonds of the Norbornane System: Formation of a C–C Bond at the Bridgehead Carbon and Bridgehead Quaternary Stereocenter | en_US |
| dc.type | Article | en_US |