Synthesis, crystal structure and catecholase activity of a vanadium(V) Schiff base complex
| dc.contributor.author | Yadav, H.R. | |
| dc.contributor.author | Choudhury, A.R. | |
| dc.date.accessioned | 2020-12-03T07:21:22Z | |
| dc.date.available | 2020-12-03T07:21:22Z | |
| dc.date.issued | 2016 | |
| dc.description | Only IISERM authors are available in the record. | |
| dc.description.abstract | An X-ray structurally characterized vanadium(V) complex, [VO2(L–H)] [L–H = H2L derived ligand (H2L = N,N′-(salicyaldimine)-1,3-diaminopropan-2-ol], was found to behave as an effective catalyst towards the oxidation of 3,5-di-tert-butylcatechol in methanol to its corresponding quinone derivative in aerial oxygen. The reaction follows Michaelis–Menten enzymatic reaction kinetics with a turnover number (Kcat) of 2.063 × 103 h−1. | en_US |
| dc.identifier.citation | Polyhedron, 111, pp.118-122. | en_US |
| dc.identifier.other | https://doi.org/10.1016/j.poly.2016.03.033 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0277538716300237 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2564 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier | en_US |
| dc.subject | Vanadium Schiff base | en_US |
| dc.subject | X-ray structure | en_US |
| dc.subject | 51V NMR | en_US |
| dc.title | Synthesis, crystal structure and catecholase activity of a vanadium(V) Schiff base complex | en_US |
| dc.type | Article | en_US |