N-Heterocyclic carbene catalysed 1,6-hydrophosphonylation of p-quinone methides and fuchsones: an atom economical route to unsymmetrical diaryl- and triarylmethyl phosphonates
| dc.contributor.author | Arde, Panjab | |
| dc.contributor.author | Anand, R.V. | |
| dc.date.accessioned | 2020-12-03T09:44:46Z | |
| dc.date.available | 2020-12-03T09:44:46Z | |
| dc.date.issued | 2016 | |
| dc.description.abstract | A convenient organocatalytic approach to access unsymmetrical diaryl- and triarylmethyl phosphonates using NHC as a Brønsted base catalyst is described. This atom-economical protocol enables the installation of phosphonate groups on p-quinone methides and fuchsones through a 1,6-conjugate addition of dialkylphosphites, and the corresponding phosphonates were obtained in excellent yields. | en_US |
| dc.identifier.citation | Organic and Biomolecular Chemistry, 14(24), pp. 5550-5554 | en_US |
| dc.identifier.other | DOI: 10.1039/C6OB00289G | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlehtml/2016/ob/c6ob00289g | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2591 | |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | N-Heterocyclic | en_US |
| dc.subject | Hydrophosphonylation | en_US |
| dc.subject | Organocatalytic | en_US |
| dc.subject | Phosphonates | en_US |
| dc.title | N-Heterocyclic carbene catalysed 1,6-hydrophosphonylation of p-quinone methides and fuchsones: an atom economical route to unsymmetrical diaryl- and triarylmethyl phosphonates | en_US |
| dc.type | Article | en_US |