Expedient access to unsymmetrical triarylmethanes through N-heterocyclic carbene catalysed 1,6-conjugate addition of 2-naphthols to para-quinone methides
| dc.contributor.author | Arde, Panjab | |
| dc.contributor.author | Anand, R.V. | |
| dc.date.accessioned | 2020-12-03T09:21:25Z | |
| dc.date.available | 2020-12-03T09:21:25Z | |
| dc.date.issued | 2016 | |
| dc.description.abstract | The utility of N-heterocyclic carbene as a Brønsted base catalyst for the synthesis of functionalised unsymmetrical triarylmethanes from 2-naphthol and para-quinone methides is described. This protocol allows the installation of naphthyl substituents on p-quinone methides through 1,6-conjugate addition to deliver the unsymmetrical triarylmethanes in good to excellent yields. Mild reaction conditions and 100% atom economy make this method synthetically advantageous over the other hitherto known methods. | en_US |
| dc.identifier.citation | RSC Advances, 6(81), pp. 77111-77115 | en_US |
| dc.identifier.other | https://doi.org/10.1039/C6RA11116E | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2016/RA/C6RA11116E#!divAbstract | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2583 | |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | Triarylmethanes | en_US |
| dc.subject | N-heterocyclic | en_US |
| dc.subject | 2-naphthols | en_US |
| dc.subject | Para -quinone methides | en_US |
| dc.title | Expedient access to unsymmetrical triarylmethanes through N-heterocyclic carbene catalysed 1,6-conjugate addition of 2-naphthols to para-quinone methides | en_US |
| dc.type | Article | en_US |