Diastereoselective palladium-catalyzed functionalization of prochiral C(sp3)–H bonds of aliphatic and alicyclic compounds
| dc.contributor.author | Babu, Srinivasarao Arulananda | |
| dc.contributor.author | Aggarwal, Yashika | |
| dc.contributor.author | Patel, Pooja | |
| dc.contributor.author | Tomar, Radha | |
| dc.date.accessioned | 2023-08-16T06:45:39Z | |
| dc.date.available | 2023-08-16T06:45:39Z | |
| dc.date.issued | 2022 | |
| dc.description | Only IISERM authors are available in the record | en_US |
| dc.description.abstract | We highlight the reported developments of the palladium-catalyzed C–H activation and functionalization of the inactive/unreactive prochiral C(sp3)–H bonds of aliphatic and alicyclic compounds. There exist numerous classical methods for generating contiguous stereogenic centers in a compound with a high degree of stereocontrol. Along similar lines, the Pd(II)-catalyzed, directing group-aided functionalization of inactive prochiral/diastereotopic C(sp3)–H bonds have been exploited to accomplish the stereoselective construction of stereo-arrays in organic compounds. We present a concise discussion on how specific strategies consisting of Pd(II)-catalyzed, directing group-aided C(sp3)–H functionalization have been utilized to generate two or more stereogenic centers in aliphatic and alicyclic compounds. | en_US |
| dc.identifier.citation | Chemical Communications, 58(16), 2612-2633 | en_US |
| dc.identifier.uri | https://doi.org/10.1039/d1cc05649b | |
| dc.identifier.uri | http://hdl.handle.net/123456789/4713 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | palladium-catalyzed C–H | en_US |
| dc.subject | Diastereoselective | en_US |
| dc.title | Diastereoselective palladium-catalyzed functionalization of prochiral C(sp3)–H bonds of aliphatic and alicyclic compounds | en_US |
| dc.type | Article | en_US |