Erratum: Palladium-catalysed 5-: Endo-trig allylic (hetero)arylation (Chem. Sci. (2020) 11 (4948-4953) DOI: 10.1039/D0SC01932A)
| dc.contributor.author | Singh, Bhupinder | |
| dc.contributor.author | Bankar, S.K. | |
| dc.contributor.author | Kumar, K. | |
| dc.contributor.author | Ramasastry, S.S.V. | |
| dc.date.accessioned | 2020-12-23T09:29:24Z | |
| dc.date.available | 2020-12-23T09:29:24Z | |
| dc.date.issued | 2020 | |
| dc.description.abstract | Aer the publication of our manuscript, a reader suggested that the transformation (shown in Scheme 1) can also be described as a Nazarov-type cyclisation1 with palladium chloride acting as a Lewis acid. While we do not have any evidence at this stage tosupport the Lewis acidic behaviour of palladium chloride,2 however, a Nazarov-type mechanistic scenario is possible. The overall transformation can also be considered as an intramolecular ene-type reaction3 or as an intramolecular Friedel–Cras-type reaction, 4 although our data agrees better with the 5-endo-trig process facilitated by the LUMO umpolung.5 Further experimental and computational investigations are underway to elucidate the full mechanistic details | en_US |
| dc.identifier.citation | Chemical Science, 11(33) PP. 9026-9027. | en_US |
| dc.identifier.other | 10.1039/d0sc90169e | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc90169e#!divAbstract | |
| dc.identifier.uri | http://hdl.handle.net/123456789/3330 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | Palladium-catalysed 5 | en_US |
| dc.subject | Endo-trig allylic (hetero)arylation | en_US |
| dc.title | Erratum: Palladium-catalysed 5-: Endo-trig allylic (hetero)arylation (Chem. Sci. (2020) 11 (4948-4953) DOI: 10.1039/D0SC01932A) | en_US |
| dc.type | Article | en_US |