Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids
| dc.contributor.author | Singh, Bara | |
| dc.contributor.author | Bankar, Siddheshwar K. | |
| dc.contributor.author | Ramasastry, S. S. V. | |
| dc.date.accessioned | 2023-08-19T13:11:25Z | |
| dc.date.available | 2023-08-19T13:11:25Z | |
| dc.date.issued | 2022 | |
| dc.description | Only IISER Mohali authors are available in the record. | en_US |
| dc.description.abstract | We describe the palladium-catalyzed Nazarov-type cyclization of easily accessible (hetero)arylallyl acetates to pentannulated (hetero)arenes. This method provides ready access to various types of bi-, tri-, tetra-, and pentacyclic cyclopentanoids under neutral conditions. The synthetic utility is further demonstrated in the first total synthesis of β-diasarone and several other complex cyclopentanoids relevant to medicinal chemistry and materials science. | en_US |
| dc.identifier.citation | Organic Letters, 24(4), 1043-1048. | en_US |
| dc.identifier.uri | https://doi.org/10.1021/acs.orglett.1c04243 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/4909 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | ACS Publications | en_US |
| dc.subject | Pd-Catalyzed Nazarov-Type Cyclization | en_US |
| dc.subject | Total Synthesis of β-Diasarone | en_US |
| dc.subject | Complex Cyclopentanoids | en_US |
| dc.title | Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids | en_US |
| dc.type | Article | en_US |