Cyclic (Alkyl)amino Carbene Based Iron Catalyst for Regioselective Dimerization of Terminal Arylalkynes
| dc.contributor.author | Adhikari, D. | |
| dc.contributor.author | Mandal, S.K. | |
| dc.date.accessioned | 2020-12-01T06:34:37Z | |
| dc.date.available | 2020-12-01T06:34:37Z | |
| dc.date.issued | 2016 | |
| dc.description | Only IISERM authors are available in the record. | |
| dc.description.abstract | [(cAAC)Fe(CO)4] (1) catalyzed head-to-head dimerization of terminal arylalkynes toward conjugated enynes in very high yield and high E selectivity (up to 84:16 E:Z). The protocol can be performed under extremely low catalyst loading down to 0.01 mol %, resulting in a high TON of 6500. A mechanistic pathway for arylalkyne dimerization has been proposed on the basis of a well-defined catalyst, an isolable intermediate, and quantum chemical calculations. | en_US |
| dc.identifier.citation | Organometallics, 35(21), pp.3775–3780 | en_US |
| dc.identifier.other | https://doi.org/10.1021/acs.organomet.6b00703 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.organomet.6b00703 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2416 | |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.subject | Catalyzed | en_US |
| dc.subject | Head-to-head dimerization | en_US |
| dc.subject | Terminal | en_US |
| dc.subject | Arylalkynes | en_US |
| dc.title | Cyclic (Alkyl)amino Carbene Based Iron Catalyst for Regioselective Dimerization of Terminal Arylalkynes | en_US |
| dc.type | Article | en_US |