Synthesis of polysubstituted cyclopenta[b]indoles via relay gold(i)/Brønsted acid catalysis
| dc.contributor.author | Dhiman, Seema | |
| dc.contributor.author | Ramasastry, S.S.V. | |
| dc.date.accessioned | 2020-12-11T06:05:41Z | |
| dc.date.available | 2020-12-11T06:05:41Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | An efficient relay catalytic process involving Au(I)/Brønsted acid to access various polysubstituted cyclopentannulated indoles from easily accessible 1-(2-aminophenyl)prop-2-ynols and readily available 1,3-dicarbonyls has been developed. In an unprecedented event, the intermediate 2-indolylmethyl cations undergo the cation-Ene reaction with various 1,3-dicarbonyls followed by an intramolecular Friedel–Crafts-type reaction generating functionalized cyclopenta[b]indoles. | en_US |
| dc.identifier.citation | Chemical Communications, 51(3) pp. 557-560. | en_US |
| dc.identifier.other | 10.1039/c4cc08174a | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2015/cc/c4cc08174a#!divAbstract | |
| dc.identifier.uri | http://hdl.handle.net/123456789/3020 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | Synthesis | en_US |
| dc.subject | polysubstituted cyclopenta[b] | en_US |
| dc.subject | gold(i)/Brønsted acid | en_US |
| dc.title | Synthesis of polysubstituted cyclopenta[b]indoles via relay gold(i)/Brønsted acid catalysis | en_US |
| dc.type | Article | en_US |