Bis(amino)cyclopropenylidene-Catalyzed 1,6-Conjugate Addition of Aromatic Aldehydes to para-Quinone Methides: Expedient Access to α,α′-Diarylated Ketones
| dc.contributor.author | Ramanjaneyulu, B.T. | |
| dc.contributor.author | Mahesh, S. | |
| dc.contributor.author | Anand, R.V. | |
| dc.date.accessioned | 2020-12-08T10:09:37Z | |
| dc.date.available | 2020-12-08T10:09:37Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | A bis(amino)cyclopropenylidene-catalyzed direct method for the synthesis of α,α′-diarylated ketones from aromatic as well as heteroaromatic aldehydes has been developed. This unprecedented organocatalytic protocol offers access to a wide range of α,α′-diarylated ketones in moderate to excellent yields under mild conditions through umpolung of aldehydes followed by 1,6-conjugate addition with para-quinone methides. | en_US |
| dc.identifier.citation | Organic Letters, 17(16) | en_US |
| dc.identifier.other | 10.1021/acs.orglett.5b01724 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.orglett.5b01724 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2830 | |
| dc.language.iso | en_US | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.subject | Carbonyls | en_US |
| dc.subject | Chemical reactions | en_US |
| dc.subject | Aromatic compounds | en_US |
| dc.subject | etones | en_US |
| dc.title | Bis(amino)cyclopropenylidene-Catalyzed 1,6-Conjugate Addition of Aromatic Aldehydes to para-Quinone Methides: Expedient Access to α,α′-Diarylated Ketones | en_US |
| dc.type | Article | en_US |