B(C6F5)3 catalysed reduction of para-quinone methides and fuchsones to access unsymmetrical diaryl- and triarylmethanes: elaboration to beclobrate
| dc.contributor.author | Mahesh, S. | |
| dc.contributor.author | Anand, R.V. | |
| dc.date.accessioned | 2020-12-04T05:03:18Z | |
| dc.date.available | 2020-12-04T05:03:18Z | |
| dc.date.issued | 2017 | |
| dc.description.abstract | A mild and efficient method for the synthesis of unsymmetrical diaryl- and triarylmethanes through a B(C6F5)3 catalyzed reduction of para-quinone methides and fuchsones respectively, using the Hantzsch ester as a reducing source has been developed. Detailed mechanistic investigations revealed that the reaction actually proceeds through a Lewis acid–base pair complex derived from B(C6F5)3 and the Hantzsch ester. | en_US |
| dc.identifier.citation | Organic and Biomolecular Chemistry, 15(39), pp. 8393-8401 | en_US |
| dc.identifier.other | https://doi.org/10.1039/C7OB02007D | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2017/ob/c7ob02007d#!divAbstract | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2638 | |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | Beclobrate | en_US |
| dc.subject | Triarylmethanes | en_US |
| dc.subject | para-quinone methides | en_US |
| dc.subject | B(C6F5)3 | en_US |
| dc.title | B(C6F5)3 catalysed reduction of para-quinone methides and fuchsones to access unsymmetrical diaryl- and triarylmethanes: elaboration to beclobrate | en_US |
| dc.type | Article | en_US |