Facile access to novel chromeno-2,6,9-trioxabicyclo[3.3.1]nonadienes via tandem nucleophilic substitution and [4+2] hetero Diels–Alder reaction: experimental and theoretical study
| dc.contributor.author | Shukla, Matsyendranath | |
| dc.contributor.author | Dorai, K. | |
| dc.date.accessioned | 2020-12-10T07:24:47Z | |
| dc.date.available | 2020-12-10T07:24:47Z | |
| dc.date.issued | 2013 | |
| dc.description | Only IISERM authors are available in the record. | |
| dc.description.abstract | An efficient synthesis of novel chromeno-2,6,9-trioxabicyclo-[3.3.1]nonadienes (CTOBN) scaffolds was achieved by mild base mediated reaction of 4-chloro-3-formylcoumarin and o-hydroxyacetophenones. The structure of the product was confirmed by X-ray analysis and the proposed mechanism was validated computationally at B3LYP/6-31G(d) level. | en_US |
| dc.identifier.citation | Tetrahedron, 69(9), pp.2142-2149. | en_US |
| dc.identifier.other | https://doi.org/10.1016/j.tet.2013.01.002 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0040402013000203 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/2963 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier | en_US |
| dc.subject | Chromeno-2,6,9-trioxabicyclo[3.3.1]nonadienes | en_US |
| dc.subject | 4-Chloro-3-formylcoumarin | en_US |
| dc.subject | o-Hydroxyacetophenones | en_US |
| dc.subject | DFT | en_US |
| dc.title | Facile access to novel chromeno-2,6,9-trioxabicyclo[3.3.1]nonadienes via tandem nucleophilic substitution and [4+2] hetero Diels–Alder reaction: experimental and theoretical study | en_US |
| dc.type | Article | en_US |