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http://hdl.handle.net/123456789/1844| Title: | 1,6-Hydroolefination and Cascade Cyclization of p-Quinone Methides with Styrenes: Total Synthesis of (±)-Isopaucifloral F |
| Authors: | Jadhav, A.S. Pankhade, Y.A. Hazra, R. Anand, R.V. |
| Keywords: | Cyclization Cascade cyclization Diarylmethanes p-Quinone methides |
| Issue Date: | 2018 |
| Publisher: | American Chemical Society |
| Citation: | Journal of Organic Chemistry, 83(17), pp. 10107–10119 |
| Abstract: | A Lewis acid-catalyzed intermolecular 1,6-hydroolefination of p-quinone methides with styrenes leading to vinyl diarylmethanes and indenes has been developed. This protocol was also elaborated to the total synthesis of (±)-isopaucifloral F. Besides, interestingly, the reaction between 2-alkynylated p-quinone methides and styrenes provided a straightforward access to dihydrobenzo[a]fluorene derivatives in one pot with 100% atom-economy |
| URI: | https://pubs.acs.org/doi/10.1021/acs.joc.8b01401 http://hdl.handle.net/123456789/1844 |
| Appears in Collections: | Research Articles |
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