Organocatalytic γ′[C(sp3)–H] Functionalization of Ynones: An Unusual Approach for the Cyclopentannulation of Benzothiophenes

Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/2059

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DC Field	Value	Language
dc.contributor.author	Grover, J.	-
dc.contributor.author	Raghu, M.	-
dc.contributor.author	Hazra, R.	-
dc.contributor.author	Mondal, A.	-
dc.contributor.author	Ramasastry, S.S.V.	-
dc.date.accessioned	2020-11-23T10:44:01Z	-
dc.date.available	2020-11-23T10:44:01Z	-
dc.date.issued	2018	-
dc.identifier.citation	Synthesis (Germany), 50(7), pp. 1462-1470	en_US
dc.identifier.other	10.1055/s-0036-1591526	-
dc.identifier.uri	https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0036-1591526	-
dc.identifier.uri	http://hdl.handle.net/123456789/2059	-
dc.description.abstract	An efficient organocatalytic approach for the cyclopenta[b]annulation of benzothiophenes via γ′[C(sp3)–H] functionalization of ynones is described. Nucleophilic addition of an organophosphine to the designed ynones generates heteroaryl-based ortho-quinodimethanes (oQDMs), which undergo carbocyclization to provide a variety of cyclopenta-fused benzothiophenes. This approach also constitutes an unusual organophosphine-catalyzed intramolecular hydroalkylation of ynones.	en_US
dc.language.iso	en	en_US
dc.publisher	Georg Thieme Verlag	en_US
dc.subject	Organophosphines	en_US
dc.subject	Hydroalkylation	en_US
dc.subject	Cyclopentannulation	en_US
dc.subject	Ynones	en_US
dc.subject	Benzothiophenes	en_US
dc.title	Organocatalytic γ′[C(sp3)–H] Functionalization of Ynones: An Unusual Approach for the Cyclopentannulation of Benzothiophenes	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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