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Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/2232
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dc.contributor.authorBawari, D.-
dc.contributor.authorGoswami, Bhupendra-
dc.contributor.authorSabari, R.S.V.-
dc.contributor.authorThakur, Sandeep Kumar-
dc.contributor.authorChoudhury, A.R.-
dc.contributor.authorSingh, Sanjay-
dc.date.accessioned2020-11-26T04:17:55Z-
dc.date.available2020-11-26T04:17:55Z-
dc.date.issued2018-
dc.identifier.citationDalton Transactions, 47(18), pp. 6274-6278en_US
dc.identifier.otherhttps://doi.org/10.1039/C7DT04589A-
dc.identifier.urihttps://pubs.rsc.org/en/content/articlelanding/2018/dt/c7dt04589a#!divAbstract-
dc.identifier.urihttp://hdl.handle.net/123456789/2232-
dc.descriptionOnly IISERM authors are available in the record.-
dc.description.abstractThis study demonstrates the first synthesis of cyclic (alkyl)(amino)carbene (cAAC) adducts of Hg(ii), [cAACMe·HgBr(μ-Br)]2 (1a) and [cAACcy·HgBr(μ-Br)]2 (1b). Adduct 1b catalyzes intermolecular hydroamination of aromatic alkynes and amines under mild conditions to afford aromatic imines. The quest to prepare an electrophilic Hg(ii) complex resulted in the synthesis of cationic [(cAACcy)2Hg(H2O)]2+2[NO3]- (3) by reacting 1b with AgNO3en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectCarbenesen_US
dc.subjectHeterocyclicsen_US
dc.subjectSuzuki Reactionen_US
dc.titleNeutral and cationic cyclic (alkyl)(amino)carbene mercury [cAAC–Hg(ii)] complexes: scope of hydroamination of alkynes with organomercury compoundsen_US
dc.typeArticleen_US
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