Please use this identifier to cite or link to this item:
http://hdl.handle.net/123456789/2260| Title: | Facile Access to Cyclopentadienes via Catalytic Intramolecular Palladium-Ene Reaction of 2,4-Pentadienyl Acetates |
| Authors: | Bharadwaj, S.K. Bankar, S.K. Ramasastry, S.S.V. |
| Keywords: | Tsuji–Trost reaction Metallo-ene reaction Cyclopentanes Iso-Nazarov reaction Annulation |
| Issue Date: | 2018 |
| Publisher: | Georg Thieme Verlag |
| Citation: | Synlett, 29(19), pp. 2456-2460 |
| Abstract: | We have recently disclosed a palladium-catalyzed Trost–Oppolzer type Alder-ene reaction of 2,4-pentadienyl acetates for the synthesis of highly substituted cyclopentadienes and cyclopentene-fused aromatics. The overall transformation also represents an acid-free iso-Nazarov type cyclization. Herein, we provide the hypothesis and rationale behind this work, while highlighting the seminal contributions of Trost, Oppolzer and others towards the development of the palladium-ene reaction. |
| URI: | https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0037-1610552 http://hdl.handle.net/123456789/2260 |
| Appears in Collections: | Research Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Need to add pdf.odt | 8.63 kB | OpenDocument Text | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.