Frontispiece: Cyclopenta[b]annulation of Heteroarenes by Organocatalytic γ′[C(sp3)−H] Functionalization of Ynones

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DC Field	Value	Language
dc.contributor.author	Raghu, M.	-
dc.contributor.author	Grover, J.	-
dc.contributor.author	Ramasastry, S.S.V.	-
dc.date.accessioned	2020-12-01T04:12:58Z	-
dc.date.available	2020-12-01T04:12:58Z	-
dc.date.issued	2016	-
dc.identifier.citation	Chemistry - A European Journal, 22(51).	en_US
dc.identifier.other	https://doi.org/10.1002/chem.201685161	-
dc.identifier.uri	https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201685161	-
dc.identifier.uri	http://hdl.handle.net/123456789/2390	-
dc.description.abstract	Intramolecular Hydroalkylation Organocatalytic γ’[C(sp3)−H] functionalization of ynones has been achieved for the first time. Nucleophilic addition of an organophosphine to the designed ynones leads to the formation of heteroaryl‐based ortho‐quinodimethane (oQDM) intermediates, which undergo an unusual carbocyclization to provide functionalized cyclopenta‐fused heteroarenes. The present study can have potential implications on the development of new organocatalytic C(sp3)−H‐functionalization pathways.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim	en_US
dc.subject	Cyclopentannulation	en_US
dc.subject	Heterocycles	en_US
dc.subject	Hydroalkylation	en_US
dc.subject	Organophosphines	en_US
dc.title	Frontispiece: Cyclopenta[b]annulation of Heteroarenes by Organocatalytic γ′[C(sp3)−H] Functionalization of Ynones	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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