Cyclic (Alkyl)amino Carbene Based Iron Catalyst for Regioselective Dimerization of Terminal Arylalkynes

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DC Field	Value	Language
dc.contributor.author	Adhikari, D.	-
dc.contributor.author	Mandal, S.K.	-
dc.date.accessioned	2020-12-01T06:34:37Z	-
dc.date.available	2020-12-01T06:34:37Z	-
dc.date.issued	2016	-
dc.identifier.citation	Organometallics, 35(21), pp.3775–3780	en_US
dc.identifier.other	https://doi.org/10.1021/acs.organomet.6b00703	-
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/acs.organomet.6b00703	-
dc.identifier.uri	http://hdl.handle.net/123456789/2416	-
dc.description	Only IISERM authors are available in the record.	-
dc.description.abstract	[(cAAC)Fe(CO)4] (1) catalyzed head-to-head dimerization of terminal arylalkynes toward conjugated enynes in very high yield and high E selectivity (up to 84:16 E:Z). The protocol can be performed under extremely low catalyst loading down to 0.01 mol %, resulting in a high TON of 6500. A mechanistic pathway for arylalkyne dimerization has been proposed on the basis of a well-defined catalyst, an isolable intermediate, and quantum chemical calculations.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Catalyzed	en_US
dc.subject	Head-to-head dimerization	en_US
dc.subject	Terminal	en_US
dc.subject	Arylalkynes	en_US
dc.title	Cyclic (Alkyl)amino Carbene Based Iron Catalyst for Regioselective Dimerization of Terminal Arylalkynes	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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