Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/2547
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dc.contributor.authorSingh, Sanjay-
dc.date.accessioned2020-12-03T05:47:55Z-
dc.date.available2020-12-03T05:47:55Z-
dc.date.issued2016-
dc.identifier.citationChemical Communications, 52(62), pp. 9683-9686en_US
dc.identifier.otherhttps://doi.org/10.1039/C6CC04805F-
dc.identifier.urihttps://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc04805f#!divAbstract-
dc.identifier.urihttp://hdl.handle.net/123456789/2547-
dc.descriptionOnly IISERM authors are available in the record.-
dc.description.abstractDeprotonation of the thialdiphosphazane [SPH(μ-NtBu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-NtBu)]22-, which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]22- ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the coordinated metal centre and that its multidentate nature can be exploited to construct large cage architectures.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectDeprotonationen_US
dc.subjectCluster formationen_US
dc.subjectSupramolecular chemistryen_US
dc.subjectPrecursoren_US
dc.titleA versatile hard–soft N/S-ligand for metal coordination and cluster formationen_US
dc.typeArticleen_US
Appears in Collections:Research Articles

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