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http://hdl.handle.net/123456789/2547| Title: | A versatile hard–soft N/S-ligand for metal coordination and cluster formation |
| Authors: | Singh, Sanjay |
| Keywords: | Deprotonation Cluster formation Supramolecular chemistry Precursor |
| Issue Date: | 2016 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 52(62), pp. 9683-9686 |
| Abstract: | Deprotonation of the thialdiphosphazane [SPH(μ-NtBu)]2 with a range of metal-bases gives the stable dianion [S-P(μ-NtBu)]22-, which is valence-isoelectronic with the widely-used [RN-P(μ-NR)]22- ligand. Structural studies show that the new ligand has adaptable hard-soft character with respect to the coordinated metal centre and that its multidentate nature can be exploited to construct large cage architectures. |
| Description: | Only IISERM authors are available in the record. |
| URI: | https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc04805f#!divAbstract http://hdl.handle.net/123456789/2547 |
| Appears in Collections: | Research Articles |
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