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http://hdl.handle.net/123456789/2564| Title: | Synthesis, crystal structure and catecholase activity of a vanadium(V) Schiff base complex |
| Authors: | Yadav, H.R. Choudhury, A.R. |
| Keywords: | Vanadium Schiff base X-ray structure 51V NMR |
| Issue Date: | 2016 |
| Publisher: | Elsevier |
| Citation: | Polyhedron, 111, pp.118-122. |
| Abstract: | An X-ray structurally characterized vanadium(V) complex, [VO2(L–H)] [L–H = H2L derived ligand (H2L = N,N′-(salicyaldimine)-1,3-diaminopropan-2-ol], was found to behave as an effective catalyst towards the oxidation of 3,5-di-tert-butylcatechol in methanol to its corresponding quinone derivative in aerial oxygen. The reaction follows Michaelis–Menten enzymatic reaction kinetics with a turnover number (Kcat) of 2.063 × 103 h−1. |
| Description: | Only IISERM authors are available in the record. |
| URI: | https://www.sciencedirect.com/science/article/pii/S0277538716300237 http://hdl.handle.net/123456789/2564 |
| Appears in Collections: | Research Articles |
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