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http://hdl.handle.net/123456789/2591| Title: | N-Heterocyclic carbene catalysed 1,6-hydrophosphonylation of p-quinone methides and fuchsones: an atom economical route to unsymmetrical diaryl- and triarylmethyl phosphonates |
| Authors: | Arde, Panjab Anand, R.V. |
| Keywords: | N-Heterocyclic Hydrophosphonylation Organocatalytic Phosphonates |
| Issue Date: | 2016 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Organic and Biomolecular Chemistry, 14(24), pp. 5550-5554 |
| Abstract: | A convenient organocatalytic approach to access unsymmetrical diaryl- and triarylmethyl phosphonates using NHC as a Brønsted base catalyst is described. This atom-economical protocol enables the installation of phosphonate groups on p-quinone methides and fuchsones through a 1,6-conjugate addition of dialkylphosphites, and the corresponding phosphonates were obtained in excellent yields. |
| URI: | https://pubs.rsc.org/en/content/articlehtml/2016/ob/c6ob00289g http://hdl.handle.net/123456789/2591 |
| Appears in Collections: | Research Articles |
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