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http://hdl.handle.net/123456789/2638| Title: | B(C6F5)3 catalysed reduction of para-quinone methides and fuchsones to access unsymmetrical diaryl- and triarylmethanes: elaboration to beclobrate |
| Authors: | Mahesh, S. Anand, R.V. |
| Keywords: | Beclobrate Triarylmethanes para-quinone methides B(C6F5)3 |
| Issue Date: | 2017 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Organic and Biomolecular Chemistry, 15(39), pp. 8393-8401 |
| Abstract: | A mild and efficient method for the synthesis of unsymmetrical diaryl- and triarylmethanes through a B(C6F5)3 catalyzed reduction of para-quinone methides and fuchsones respectively, using the Hantzsch ester as a reducing source has been developed. Detailed mechanistic investigations revealed that the reaction actually proceeds through a Lewis acid–base pair complex derived from B(C6F5)3 and the Hantzsch ester. |
| URI: | https://pubs.rsc.org/en/content/articlelanding/2017/ob/c7ob02007d#!divAbstract http://hdl.handle.net/123456789/2638 |
| Appears in Collections: | Research Articles |
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| Need to add pdf.odt | 7.9 kB | OpenDocument Text | View/Open |
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