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http://hdl.handle.net/123456789/2642
Title: | Construction of Tertiary Amides: NiII-Catalyzed N-Arylation of Secondary Acyclic Amides (2-Picolinamides) with Aryl Halides |
Authors: | Sankar, Rathinam Babu, S.A. |
Keywords: | amides cross-coupling reactions picolinamides |
Issue Date: | 2017 |
Publisher: | Wiley-VCH Verlag |
Citation: | Asian Journal of Organic Chemistry, 6(3) |
Abstract: | NiII-catalyzed C−N cross-coupling reaction of secondary acyclic amides (2-picolinamides, which were derived from 2-picolinic acid and amines) and aryl halides for the construction of tertiary amides has been reported. Relatively inexpensive NiCl2 was used as the catalyst for the N-arylation of various 2-picolinamides (secondary acyclic amides), in which the 2-picolinamide unit plausibly served as an internal ligand. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
URI: | https://onlinelibrary.wiley.com/doi/full/10.1002/ajoc.201600596 http://hdl.handle.net/123456789/2642 |
Appears in Collections: | Research Articles |
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