An enantioselective organocatalytic intramolecular Morita–Baylis–Hillman (IMBH) reaction of dienones, and elaboration of the IMBH adducts to fluorenones

Satpathi, B.; Wagulde, S.V.; Ramasastry, S.S.V.

Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/2644

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DC Field	Value	Language
dc.contributor.author	Satpathi, B.	-
dc.contributor.author	Wagulde, S.V.	-
dc.contributor.author	Ramasastry, S.S.V.	-
dc.date.accessioned	2020-12-04T05:28:33Z	-
dc.date.available	2020-12-04T05:28:33Z	-
dc.date.issued	2017	-
dc.identifier.citation	Chemical Communications, 53(57), pp. 8042-8045	en_US
dc.identifier.other	https://doi.org/10.1039/C7CC02524F	-
dc.identifier.uri	https://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc02524f#!divAbstract	-
dc.identifier.uri	http://hdl.handle.net/123456789/2644	-
dc.description.abstract	An enantioselective organocatalytic intramolecular Morita–Baylis–Hillman (IMBH) reaction of dienones is reported for the first time. This has been achieved by incorporating entropy and synergy considerations during the substrate design. The reaction conditions are thoroughly verified for an efficient synthesis of highly functionalised cyclopenta-fused arenes and heteroarenes in excellent yields and enantioselectivities. The synthetic utility of the IMBH-adducts has been demonstrated by transforming them into 3,4-disubstituted fluorenones in a serendipitous manner.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Enantioselective	en_US
dc.subject	Organocatalytic	en_US
dc.subject	IMBH	en_US
dc.subject	Fluorenones	en_US
dc.title	An enantioselective organocatalytic intramolecular Morita–Baylis–Hillman (IMBH) reaction of dienones, and elaboration of the IMBH adducts to fluorenones	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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