Exploitation of Intramolecular Glaser-Eglinton-Hay Macrocyclization for the Synthesis of New Classes of Optically Active Aza-Oxo-Thia Polyether Macrocycles from Amino Alcohol Building Blocks

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DC Field	Value	Language
dc.contributor.author	Babu, S.A.	-
dc.date.accessioned	2020-12-04T11:26:20Z	-
dc.date.available	2020-12-04T11:26:20Z	-
dc.date.issued	2017	-
dc.identifier.citation	Synlett, 28(2)	en_US
dc.identifier.other	10.1055/s-0036-1588329	-
dc.identifier.uri	https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0036-1588329	-
dc.identifier.uri	http://hdl.handle.net/123456789/2703	-
dc.description.abstract	We report an intramolecular Glaser-Eglinton-Hay coupling as an unprecedented route for assembling optically active aza-oxo polyether macrocycles containing a 1,3-diyne unit from enantiopure amino alcohol building blocks and suitable linkers. Furthermore, the conversion of the 1,3-diyne unit of the aza-oxo polyether macrocycles into a thiophene ring led to the assembly of new classes of optically active aza-oxa-thia (heterotopic) polyether macrocycle analogues of classical 18-C-6 and 18-C-5 systems	en_US
dc.language.iso	en_US	en_US
dc.publisher	Georg Thieme Verlag	en_US
dc.subject	alkynes	en_US
dc.subject	amino alcohols	en_US
dc.subject	cross-coupling	en_US
dc.subject	crown compounds	en_US
dc.title	Exploitation of Intramolecular Glaser-Eglinton-Hay Macrocyclization for the Synthesis of New Classes of Optically Active Aza-Oxo-Thia Polyether Macrocycles from Amino Alcohol Building Blocks	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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