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http://hdl.handle.net/123456789/2863Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Parella, R. | - |
| dc.contributor.author | Gopalakrishnan, B. | - |
| dc.contributor.author | Babu, S.A. | - |
| dc.date.accessioned | 2020-12-09T05:46:08Z | - |
| dc.date.available | 2020-12-09T05:46:08Z | - |
| dc.date.issued | 2013 | - |
| dc.identifier.citation | Organic Letters,15(13), pp. 3238-3241. | en_US |
| dc.identifier.other | https://doi.org/10.1021/ol4012212 | - |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ol4012212 | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/2863 | - |
| dc.description.abstract | An auxiliary-enabled and Pd(OAc)2-catalyzed direct arylation of C(sp3)–H bonds of cyclopropanes and production of di- and trisubstituted cyclopropanecarboxamides having contiguous stereocenters are reported. The installation of aryl groups on cyclopropanecarboxamides led to the assembling of novel mono- and di- aryl-N-(quinolin-8-yl)cyclopropanecarboxamide scaffolds and mono- and di- aryl-N-(2-(methylthio)phenyl)cyclopropanecarboxamides. The stereochemistry of products was unequivocally assigned from the X-ray structures of key compounds. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.subject | Stereocenters | en_US |
| dc.subject | Auxiliary-enabled | en_US |
| dc.subject | Cyclopropanes | en_US |
| dc.title | Auxiliary-Enabled Pd-Catalyzed Direct Arylation of Methylene C(sp3)–H Bond of Cyclopropanes: Highly Diastereoselective Assembling of Di- and Trisubstituted Cyclopropanecarboxamides | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | Research Articles | |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Need to add pdf.odt | 8.63 kB | OpenDocument Text | View/Open |
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