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http://hdl.handle.net/123456789/2900
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DC Field | Value | Language |
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dc.contributor.author | Rishu | - |
dc.date.accessioned | 2020-12-09T09:18:36Z | - |
dc.date.available | 2020-12-09T09:18:36Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 785 pp. 19-25 | en_US |
dc.identifier.other | 10.1016/j.jorganchem.2015.02.024 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0022328X15000923 | - |
dc.identifier.uri | http://hdl.handle.net/123456789/2900 | - |
dc.description | Only IISERM authors are available in the record. | - |
dc.description.abstract | An efficient synthetic protocol affording symmetrical 1,2-bis(pyridine-2/3/4-yl)methyldiselanes from pyridine-2/3/4-carbaldehyde in high yields at room temperature, without using highly toxic hydrogen selenide, has been developed. The synthesis involves the reductive selenation of pyridine-2/3/4-carbaldehyde with sodium hydrogen selenide, NaHSe in the presence of piperidine hydrochloride followed by NaBH4 reduction under mild conditions. Primary screening of the anti-proliferative activity of the newly synthesized compounds against several mammalian cell lines and pathogenic strains has been carried out. The crystal structure of 1,2-bis(pyridine-3-yl)methyldiselane has been established by X-ray diffraction analysis. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | Elsevier | en_US |
dc.subject | Carbaldehyde | en_US |
dc.subject | Piperidine | en_US |
dc.subject | Selenium | en_US |
dc.subject | Diselane | en_US |
dc.title | Design, synthesis and characterization of picoline based organoselenium compounds, 1,2-bis(pyridine-2/3/4-yl)methyl diselanes: X-ray crystal structure of 1,2-bis(pyridine-3-yl)methyldiselane | en_US |
dc.type | Article | en_US |
Appears in Collections: | Research Articles |
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