(2 S)-2-[(Phenylsulfinyl)methyl]pyrrolidine-catalyzed efficient stereoselective michael addition of cyclohexanone and cyclopentanone to nitroolefins

Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/2931

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DC Field	Value	Language
dc.contributor.author	Khullar, S.	-
dc.contributor.author	Mandal, S.K.	-
dc.date.accessioned	2020-12-10T06:16:27Z	-
dc.date.available	2020-12-10T06:16:27Z	-
dc.date.issued	2013	-
dc.identifier.citation	Synthesis (Germany), 45(10), pp.1406-1413.	en_US
dc.identifier.other	10.1055/s-0032-1316917 paper	-
dc.identifier.uri	https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0032-1316917	-
dc.identifier.uri	http://hdl.handle.net/123456789/2931	-
dc.description	Only IISERM authors are available in the record.	-
dc.description.abstract	(2S)-2-[(Phenylsulfinyl)methyl]pyrrolidine, derived from l-proline, has been demonstrated as an efficient organocatalyst for the asymmetric Michael addition of cyclohexanone and cyclopentanone to β-nitrostyrenes. This pyrrolidine-based catalyst bearing a sulfoxide moiety was used to synthesize various γ-nitro carbonyl compounds in high yield (up to 97%) with excellent stereoselectivity (up to >99:1 dr and >99% ee) without the use of any additive.	en_US
dc.language.iso	en	en_US
dc.publisher	Thieme	en_US
dc.subject	Michael addition reaction	en_US
dc.subject	Organocatalyst	en_US
dc.subject	Amino sulfoxide	en_US
dc.subject	Nitroolefins	en_US
dc.title	(2 S)-2-[(Phenylsulfinyl)methyl]pyrrolidine-catalyzed efficient stereoselective michael addition of cyclohexanone and cyclopentanone to nitroolefins	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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