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http://hdl.handle.net/123456789/2934| Title: | Construction of Functionalized Carbocycles Having Contiguous Tertiary Carbinol and All‐Carbon Stereogenic Centers |
| Authors: | Reddy, C. Babu, S.A. Aslam, N.A. Rajkumar, V. |
| Keywords: | Carbocycles Diastereoselectivity Allylation Indium |
| Issue Date: | 2013 |
| Publisher: | WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
| Citation: | European Journal of Organic Chemistry, 2013(12), pp.2362-2380. |
| Abstract: | The indium‐mediated installation of a stereoarray that consists of contiguous tertiary carbinol and all‐carbon stereocenters in functionalized carbocyclic building blocks and bicyclic lactones is presented. The absolute stereochemistry of the products was established for the highly diastereofacial selective addition of allyl and propargyl indiums to α‐alkyl‐α‐(ethoxycarbonyl)cycloalkanones. |
| URI: | https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201201382 http://hdl.handle.net/123456789/2934 |
| ISSN: | https://doi.org/10.1002/ejoc.201201382 |
| Appears in Collections: | Research Articles |
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| Need to add pdf.odt | 8.63 kB | OpenDocument Text | View/Open |
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