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http://hdl.handle.net/123456789/3035| Title: | Ruthenium-Catalyzed Hydroarylation of Anilides with Alkynes: An Efficient Route to Ortho-Alkenylated Anilines |
| Authors: | Manikandan, R. Jeganmohan, M. |
| Keywords: | Hydrocarbons Chemical reactions Aromatic compounds Organic compounds Arylation |
| Issue Date: | 2014 |
| Publisher: | American Chemical Society. |
| Citation: | Organic Letters, 16(3), pp.912-915. |
| Abstract: | Acetanilides reacted with symmetrical as well as unsymmetrical alkynes in the presence of [{RuCl2(p-cymene)}2], pivalic acid, and AgSbF6 in iso-PrOH providing ortho-alkenylated acetanilides in a highly regio- and stereoselective manner. Later, ortho-alkenylated acetanilides were converted into ortho-alkenylated anilines in the presence of HCl. |
| URI: | https://pubs.acs.org/doi/10.1021/ol403666s http://hdl.handle.net/123456789/3035 |
| Appears in Collections: | Research Articles |
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