Palladium-Catalyzed Double Activation and Arylation of 2° and 3° C(sp3)–H Bonds of the Norbornane System: Formation of a C–C Bond at the Bridgehead Carbon and Bridgehead Quaternary Stereocenter

Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/3060

Full metadata record

DC Field	Value	Language
dc.contributor.author	Parella, R.	-
dc.contributor.author	Babu, S.A.	-
dc.date.accessioned	2020-12-11T10:38:51Z	-
dc.date.available	2020-12-11T10:38:51Z	-
dc.date.issued	2014	-
dc.identifier.citation	Synlett, 25(10), pp.1395-1402.	en_US
dc.identifier.other	10.1055/s-0033-1341242	-
dc.identifier.uri	https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0033-1341242	-
dc.identifier.uri	http://hdl.handle.net/123456789/3060	-
dc.description.abstract	Pd-catalyzed activation and direct arylation of both 2° and the bridgehead 3° (sp3) C-H bonds and an unprecedented C-C bond formation at the bridgehead carbon of the norbornane system are reported. The assembly of bridgehead-substituted norbornane frameworks having contiguous stereocenters was accomplished. X-ray crystal structure analysis of representative molecules unambiguously established the stereochemistry.	en_US
dc.language.iso	en	en_US
dc.publisher	Georg Thieme Verlag	en_US
dc.subject	Arylation	en_US
dc.subject	Bridgehead substitution	en_US
dc.subject	C–H activation	en_US
dc.subject	Diastereoselectivity	en_US
dc.subject	Palladium	en_US
dc.subject	Stereoselective synthesis	en_US
dc.title	Palladium-Catalyzed Double Activation and Arylation of 2° and 3° C(sp3)–H Bonds of the Norbornane System: Formation of a C–C Bond at the Bridgehead Carbon and Bridgehead Quaternary Stereocenter	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

Files in This Item:

File	Description	Size	Format
need to add pdf....odt		8.12 kB	OpenDocument Text	View/Open