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http://hdl.handle.net/123456789/3066| Title: | Magnetic Nano Fe3O4 Catalyzed Solvent-Free Stereo- and Regioselective Aminolysis of Epoxides by Amines; a Green Method for the Synthesis of β-Amino Alcohols |
| Authors: | Kumar, Amit Parella, R. Babu, S.A. |
| Keywords: | Amino alcohols Epoxides Green chemistry Nano magnetite Regioselectivity Stereoselective synthesis |
| Issue Date: | 2014 |
| Publisher: | Georg Thieme Verlag |
| Citation: | Synlett, 25(6), pp. 835-842. |
| Abstract: | We report the use of magnetic nano Fe3O4 as a mild heterogeneous catalyst for the aminolysis of epoxides with amines. The approach constitutes a green method for the formation of a variety of β-amino alcohols with very high stereo- and regioselectivity under solvent-free and ambient reaction conditions. The aminolysis of chiral epoxides with amines gave the corresponding chiral β-amino alcohols with complete inversion of stereochemistry. The magnetic nano Fe3O4 catalyst can be easily recovered and recycled. |
| URI: | https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0033-1340844 http://hdl.handle.net/123456789/3066 |
| Appears in Collections: | Research Articles |
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| need to add pdf....odt | 8.12 kB | OpenDocument Text | View/Open |
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