NHC catalysed trimethylsilylation of terminal alkynes and indoles with Ruppert's reagent under solvent free conditions

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DC Field	Value	Language
dc.contributor.author	Arde, Panjab	-
dc.contributor.author	Reddy, V.	-
dc.contributor.author	Anand, R.V.	-
dc.date.accessioned	2020-12-14T07:06:43Z	-
dc.date.available	2020-12-14T07:06:43Z	-
dc.date.issued	2014	-
dc.identifier.citation	RSC Advances, 4(91), pp.49775-49779.	en_US
dc.identifier.other	https://doi.org/10.1039/C4RA08727E	-
dc.identifier.uri	https://pubs.rsc.org/en/content/articlelanding/2014/RA/C4RA08727E#!divAbstract	-
dc.identifier.uri	http://hdl.handle.net/123456789/3105	-
dc.description.abstract	n organo-catalytic protocol for the trimethylsilylation of terminal alkynes employing Ruppert's reagent (CF3SiMe3) as a trimethylsilyl source has been developed under solvent and fluoride free conditions. This method was found to be very effective as a variety of terminal alkynes bearing aliphatic or aromatic substituents underwent smooth transformation to their corresponding silylated products in excellent yields within a few minutes using N-heterocyclic carbene as an organo-catalyst. This methodology was also applied to the chemospecific N-silylation of indoles.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Terminal alkynes	en_US
dc.subject	Trimethyl silylation	en_US
dc.subject	NHC catalysed	en_US
dc.title	NHC catalysed trimethylsilylation of terminal alkynes and indoles with Ruppert's reagent under solvent free conditions	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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