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http://hdl.handle.net/123456789/3330| Title: | Erratum: Palladium-catalysed 5-: Endo-trig allylic (hetero)arylation (Chem. Sci. (2020) 11 (4948-4953) DOI: 10.1039/D0SC01932A) |
| Authors: | Singh, Bhupinder Bankar, S.K. Kumar, K. Ramasastry, S.S.V. |
| Keywords: | Palladium-catalysed 5 Endo-trig allylic (hetero)arylation |
| Issue Date: | 2020 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Science, 11(33) PP. 9026-9027. |
| Abstract: | Aer the publication of our manuscript, a reader suggested that the transformation (shown in Scheme 1) can also be described as a Nazarov-type cyclisation1 with palladium chloride acting as a Lewis acid. While we do not have any evidence at this stage tosupport the Lewis acidic behaviour of palladium chloride,2 however, a Nazarov-type mechanistic scenario is possible. The overall transformation can also be considered as an intramolecular ene-type reaction3 or as an intramolecular Friedel–Cras-type reaction, 4 although our data agrees better with the 5-endo-trig process facilitated by the LUMO umpolung.5 Further experimental and computational investigations are underway to elucidate the full mechanistic details |
| URI: | https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc90169e#!divAbstract http://hdl.handle.net/123456789/3330 |
| Appears in Collections: | Research Articles |
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