Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/3330
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dc.contributor.authorSingh, Bhupinder-
dc.contributor.authorBankar, S.K.-
dc.contributor.authorKumar, K.-
dc.contributor.authorRamasastry, S.S.V.-
dc.date.accessioned2020-12-23T09:29:24Z-
dc.date.available2020-12-23T09:29:24Z-
dc.date.issued2020-
dc.identifier.citationChemical Science, 11(33) PP. 9026-9027.en_US
dc.identifier.other10.1039/d0sc90169e-
dc.identifier.urihttps://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc90169e#!divAbstract-
dc.identifier.urihttp://hdl.handle.net/123456789/3330-
dc.description.abstractAer the publication of our manuscript, a reader suggested that the transformation (shown in Scheme 1) can also be described as a Nazarov-type cyclisation1 with palladium chloride acting as a Lewis acid. While we do not have any evidence at this stage tosupport the Lewis acidic behaviour of palladium chloride,2 however, a Nazarov-type mechanistic scenario is possible. The overall transformation can also be considered as an intramolecular ene-type reaction3 or as an intramolecular Friedel–Cras-type reaction, 4 although our data agrees better with the 5-endo-trig process facilitated by the LUMO umpolung.5 Further experimental and computational investigations are underway to elucidate the full mechanistic detailsen_US
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectPalladium-catalysed 5en_US
dc.subjectEndo-trig allylic (hetero)arylationen_US
dc.titleErratum: Palladium-catalysed 5-: Endo-trig allylic (hetero)arylation (Chem. Sci. (2020) 11 (4948-4953) DOI: 10.1039/D0SC01932A)en_US
dc.typeArticleen_US
Appears in Collections:Research Articles

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