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http://hdl.handle.net/123456789/437
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DC Field | Value | Language |
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dc.contributor.author | Verma, Gaurav | - |
dc.date.accessioned | 2014-09-03T06:10:25Z | - |
dc.date.available | 2014-09-03T06:10:25Z | - |
dc.date.issued | 2014-09-03 | - |
dc.identifier.uri | http://hdl.handle.net/123456789/437 | - |
dc.description.abstract | Two new hexadentate ligands, N, N’, N’’, N’’’-tetrakis-(4-pyridylmethyl)-1,4-diaminobutane (4- pytpbn) and N,N’’-bis-(2-pyridylmethyl)-N’,N’’’-bis-(4-pyridylmethyl)-1,4-diaminobutane (2,4- pytpbn) have been synthesized and structurally characterized. Complexes of 4-pytpbn of the 2+ 2+ 2+ 2+ - - -general formula [M(4-pytpbn)X2], where M = Co (1, 2, 5), Cd (3), Cu (4); X = NO3 , Cl , - 2+ 2+ 2+ 2+ 2- 2- 2-ClO4 , and [M2A2(4-pytpbn)], where M = Zn (6), Cd (7) and Ni (8, 9), A = adc , fum , succ2-, have been synthesized. All these complexes have been characterized by elemental analysis, FTIR spectroscopy, thermogravimetric analysis and powder X-ray diffractometry. Single crystal X-ray analysis of the ligands and preliminary results of 1 and 2 that establish the presence of expected pores in these are also reported. | en_US |
dc.description.sponsorship | IISER M | en_US |
dc.language.iso | en | en_US |
dc.publisher | IISER M | en_US |
dc.subject | Chemistry | en_US |
dc.title | New Hexadentate Ancillary Ligands and Their Metal Organic Coordination Networks | en_US |
dc.type | Thesis | en_US |
dc.guide | Mandal, S.K. | - |
Appears in Collections: | MS-09 |
Files in This Item:
File | Description | Size | Format | |
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MS-09053.pdf | 2.56 MB | Adobe PDF | View/Open |
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