Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/4463
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dc.contributor.authorKumar, Prashant-
dc.contributor.authorNikam, Mrudula M.-
dc.contributor.authorRamasastry, S. S. V.-
dc.date.accessioned2023-08-10T10:35:18Z-
dc.date.available2023-08-10T10:35:18Z-
dc.date.issued2022-
dc.identifier.citationOrganometallics, A-Gen_US
dc.identifier.urihttps://doi.org/10.1021/acs.organomet.2c00472-
dc.identifier.urihttp://hdl.handle.net/123456789/4463-
dc.descriptionOnly IISERM authors are available in the recorden_US
dc.description.abstractUnlike that of benzyl acetates, the chemistry of benzyl gem-diacetates is rarely explored under metal catalysis. Here, we describe the first palladium-catalyzed cascade annulative allylic alkylation of benzylic gem-diacetates to access complex analogues of (hetero)arene-fused benzo[f]chromenes, which find relevance in medicinal chemistry and materials science. This synthetic feat has been achieved through the formal [3+3] heterocyclization of easily accessible (hetero)aryl gem-diacetates and readily available 2-naphthols under neutral conditions. Detailed mechanistic studies and synthetic elaborations have also been performed.en_US
dc.language.isoen_USen_US
dc.publisherACS Publicationsen_US
dc.subjectChemical reactionsen_US
dc.subjectOrganic compoundsen_US
dc.subjectColumn chromatographyen_US
dc.titlePd-Catalyzed Formal [3+3] Annulation of Benzylic gem-Diacetates: Synthesis of Various (Hetero)Arene-Fused Benzo[ f]chromenesen_US
dc.typeArticle-
Appears in Collections:Research Articles

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