Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/4589
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dc.contributor.authorRekha-
dc.contributor.authorSharma, Sonam-
dc.contributor.authorSingh, Gurdeep-
dc.contributor.authorAnand, Ramasamy Vijaya-
dc.date.accessioned2023-08-12T09:30:44Z-
dc.date.available2023-08-12T09:30:44Z-
dc.date.issued2022-
dc.identifier.citationACS Organic and Inorganic Au, 2(2), 186-196.en_US
dc.identifier.urihttps://doi.org/10.1021/acsorginorgau.1c00033-
dc.identifier.urihttp://hdl.handle.net/123456789/4589-
dc.descriptionOnly IISERM authors are available in the recorden_US
dc.description.abstractCarbocation catalysis is emerging as an important subarea of Lewis acid catalysis. Some stable and isolable carbocations have been successfully utilized as Lewis acid catalysts and promoters in many synthetic transformations. In this manuscript, we report a tropylium cation-promoted vinylogous aza-Michael addition of carbamates to para-quinone methides (QMs) to access a wide range of unsymmetrical α,α′-diarylmethyl carbamates. This mild protocol was effective for the vinylogous conjugate addition of (−)-menthyl carbamate to p-QMs, and the respective diastereomerically pure α,α′-diarylmethyl carbamate derivatives could be obtained in excellent yields and diastereoselectivities (up to >20:1 de).en_US
dc.language.isoen_USen_US
dc.publisherACS Publicationsen_US
dc.subjectAdductsen_US
dc.subjectOrganic compoundsen_US
dc.subjectCationsen_US
dc.subjectCatalystsen_US
dc.titleTropylium Salt-Promoted Vinylogous Aza-Michael Addition of Carbamates to para-Quinone Methides: Elaboration to Diastereomerically Pure α,α′-Diarylmethyl Carbamatesen_US
dc.typeArticleen_US
Appears in Collections:Research Articles

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