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http://hdl.handle.net/123456789/4713
Title: | Diastereoselective palladium-catalyzed functionalization of prochiral C(sp3)–H bonds of aliphatic and alicyclic compounds |
Authors: | Babu, Srinivasarao Arulananda Aggarwal, Yashika Patel, Pooja Tomar, Radha |
Keywords: | palladium-catalyzed C–H Diastereoselective |
Issue Date: | 2022 |
Publisher: | Royal Society of Chemistry |
Citation: | Chemical Communications, 58(16), 2612-2633 |
Abstract: | We highlight the reported developments of the palladium-catalyzed C–H activation and functionalization of the inactive/unreactive prochiral C(sp3)–H bonds of aliphatic and alicyclic compounds. There exist numerous classical methods for generating contiguous stereogenic centers in a compound with a high degree of stereocontrol. Along similar lines, the Pd(II)-catalyzed, directing group-aided functionalization of inactive prochiral/diastereotopic C(sp3)–H bonds have been exploited to accomplish the stereoselective construction of stereo-arrays in organic compounds. We present a concise discussion on how specific strategies consisting of Pd(II)-catalyzed, directing group-aided C(sp3)–H functionalization have been utilized to generate two or more stereogenic centers in aliphatic and alicyclic compounds. |
Description: | Only IISERM authors are available in the record |
URI: | https://doi.org/10.1039/d1cc05649b http://hdl.handle.net/123456789/4713 |
Appears in Collections: | Research Articles |
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