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http://hdl.handle.net/123456789/4790| Title: | Nickel-Catalyzed Selective Synthesis of α-Alkylated Ketones via Dehydrogenative Cross-Coupling of Primary and Secondary Alcohols |
| Authors: | Bains, Amreen K Biswas, Ayanangshu Adhikari, Debashis |
| Keywords: | nickel catalysis cross-coupling secon-dary alcohols radicalreaction |
| Issue Date: | 2021 |
| Publisher: | Wiley |
| Citation: | Advanced Synthesis & Catalysis, 364(1), 47–52. |
| Abstract: | Herein,we describean isolable,air-stable,homogeneous,nickel catalystthat performsdehydrogenativecross-couplingreactionbetweensecondaryand primaryalcoholsto result α-alkylatedketoneproductsselectively. The sequenceof stepsinvolvein this one-potreactionis dehydrogenationof both alcohols,condensationbetweenthe ketoneand the aldehyde,and hydrogenationof the in situ-generatedα,β-unsaturatedketone.Preliminarymechanisticinvestigationhints a radicalmechanismfollowingborrowinghydrogenreaction |
| Description: | Only IISERM authors are available in the record |
| URI: | https://onlinelibrary.wiley.com/doi/10.1002/adsc.202101077 http://hdl.handle.net/123456789/4790 |
| Appears in Collections: | Research Articles |
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