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http://hdl.handle.net/123456789/4836
Title: | Annulative Morita–Baylis–Hillman reaction to synthesise chiral dibenzocycloheptanes |
Authors: | Mondal, Atanu Shivangi Tung, Pinku Waguldea, Siddhant V. Ramasastry, S. S. V. |
Keywords: | Morita–Baylis–Hillman dibenzocycloheptanes |
Issue Date: | 2021 |
Publisher: | Publishing |
Citation: | Chemical Communications, 57(73), 9260–9263. |
Abstract: | We describe the first metal-free and organocatalytic strategy to access highly functionalised dibenzocycloheptanes via a phosphine-promoted annulative Morita–Baylis–Hillman (MBH) reaction. The method is manipulated to access to chiral dibenzocycloheptanes as well. This work represents a rare entry for the construction of seven-membered carbocycles via the MBH route. The realisation of several bioactive molecules possessing the dibenzocycloheptane core makes this an attractive strategy. |
Description: | Only IISER Mohali authors are available in the record |
URI: | https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC02765D http://hdl.handle.net/123456789/4836 |
Appears in Collections: | Research Articles |
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