Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/4902
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dc.contributor.authorSrivastava, Anjali-
dc.contributor.authorGrewal, Surbhi-
dc.contributor.authorBari, Naimat K.-
dc.contributor.authorSaraswat, Mayank-
dc.contributor.authorSinha, Sharmistha-
dc.contributor.authorVenkataramani, Sugumar-
dc.date.accessioned2023-08-19T12:19:29Z-
dc.date.available2023-08-19T12:19:29Z-
dc.date.issued2022-
dc.identifier.citationOrganic and Biomolecular Chemistry, 20(26), 5284-5292.en_US
dc.identifier.urihttps://doi.org/10.1039/d2ob00866a-
dc.identifier.urihttp://hdl.handle.net/123456789/4902-
dc.descriptionOnly IISER Mohali authors are available in the record.en_US
dc.description.abstractWe report the design, synthesis, and study of light-induced shape-changing azomacrocycles. These systems have been incorporated with azobenzene photoswitches using alkoxy tethers and triazole units to afford flexibility and binding. We envision that such azomacrocycles are capable of reversibly binding with the guest molecule. Remarkably, we have demonstrated fully light-controlled fluorescence quenching and enhancement in the monomeric emission of pyrene (guest). Such modulations have been achieved by the photoisomerization of the azomacrocycle and, in turn, host–guest interactions. Also, the azomacrocycles tend to aggregate and can also be controlled by light or heat. We uncovered such phenomena using spectroscopic, microscopic, and isothermal titration calorimetry (ITC) studies and computations.en_US
dc.language.isoen_USen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectazomacrocyclesen_US
dc.subjectexhibiting reversibleen_US
dc.subjectmodulation of pyrene fluorescence emissionen_US
dc.titleLight-controlled shape-changing azomacrocycles exhibiting reversible modulation of pyrene fluorescence emissionen_US
dc.typeArticleen_US
Appears in Collections:Research Articles

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